Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5?K and 298?K and new data on multiferroic NaFeSi2O6     

G��nther J. Redhammer  Anatoliy Senyshyn  Martin Meven  Georg Roth  Sebastian Prinz  Astrid Pachler  Gerold Tippelt  Clemens Pietzonka  Werner Treutmann  Markus Hoelzel  Bj?rn Pedersen  Georg Amthauer 《Physics and Chemistry of Minerals》2011,38(2):139-157

The compound NaFeGe₂O₆ was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe₂O₆ is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO₄ tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe₂O₆ transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO₆ octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe₂O₆ with NaFeSi₂O₆ is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.  相似文献   

Late Cretaceous-Cenozoic history of the Lake Baikal depression and formation of its unique biodiversity     

V. D. Mats  D. Yu. Shcherbakov  I. M. Efimova 《Stratigraphy and Geological Correlation》2011,19(4):404-423

Independent methods of geological and molecular-biological chronologies have made it possible to define generally corresponding stages in the geological and biological evolution of the environments and communities of Lake Baikal since the Late Cretaceous, i.e., during the last 70 myr. All the abiotic elements drastically changed during geological evolution, with destruction of existing and formation of new natural complexes. Nevertheless, some specific zones retained relicts of former settings. The resulting present-day natural complex includes elements of different ages and geneses. Similar to different natural zones of the present-day Earth, which are populated by different biocoenoses, stages in the development of abiotic elements are also characterized by different faunal and floral assemblages. Some taxa were replaced by others, and the resulting aqueous biota of Lake Baikal includes different-age and ecologically different elements. The oldest groups of Baikal organisms appeared approximately 70 Ma ago, although the largest proportion of the lake biota started forming 4–3 Ma ago in response to the most drastic changes in the abiotic elements of the environment. The youngest taxa appeared 1.8 to 0.15 Ma ago, i.e., during the period when superdeep lake environments and mountainous glaciations were developing. The chronological coincidence of main stages in development of abiotic and biotic elements of the nature indicates their relationships. Particular transformations of abiotic elements and the probable mechanism of their influence on the evolution of living communities are also considered.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987111000594     

Victor D. Mats  Tatiana I. Perepelova 《地学前缘(英文版)》2011,2(3):349-365

A new model is suggested for the history of the Baikal Rift,in deviation from the classic two-stage evolution scenario,based on a synthesis of the available data from the Baikal Basin and revised correlation between tectonic-lithological-stratigraphic complexes(TLSC) in sedimentary sections around Lake Baikal and seismic stratigraphic sequences(SSS) in the lake sediments.Unlike the previous models,the revised model places the onset of rifting during Late Cretaceous and comprises three major stages which are subdivided into several substages.The stages and the substages are separated by events of tectonic activity and stress reversal when additional compression produced folds and shear structures.The events that mark the stage boundaries show up as gaps,unconformities,and deformation features in the deposition patterns. The earliest Late Cretaceous-Oligocene stage began long before the India-Eurasia collision in a setting of diffuse extension that acted over a large territory of Asia.The NW-SE far-field pure extension produced an NE-striking half-graben oriented along an old zone of weakness at the edge of the Siberian craton.That was already the onset of rift evolution recorded in weathered lacustrine deposits on the Baikal shore and in a wedge-shaped acoustically transparent seismic unit in the lake sediments.The second stage spanning Late Oligocene-Early Pliocene time began with a stress change when the effect from the Eocene India-Eurasia collision had reached the region and became a major control of its geodynamics.The EW and NE transpression and shear from the collisional front transformed the Late Cretaceous half-graben into a U-shaped one which accumulated a deformed layered sequence of sediments.Rifting at the latest stage was driven by extension from a local source associated with hot mantle material rising to the base of the rifted crust.The asthenospheric upwarp first induced the growth of the Baikal dome and the related change from finer to coarser molasse deposition.With time,the upwarp became a more powerful stress source than the collision,and the stress vector returned to the previous NW-SE extension that changed the rift geometry back to a half-graben. The layered Late Pliocene-Quaternary subaerial tectonic-lithological-stratigraphic and the Quaternary submarine seismic stratigraphic units filling the latest half-graben remained almost undeformed.The rifting mechanisms were thus passive during two earlier stages and active during the third stage. The three-stage model of the rift history does not rule out the previous division into two major stages but rather extends its limits back into time as far as the Maastrichtian.Our model is consistent with geological, stratigraphic,structural,and geophysical data and provides further insights into the understanding of rifting in the Baikal region in particular and continental rifting in general.  相似文献   

Using sewage sludge as a sealing layer to remediate sulphidic mine tailings: a pilot-scale experiment, northern Sweden   总被引：1，自引：0，他引：1  

Peter Nason  Lena Alakangas  Björn Öhlander 《Environmental Earth Sciences》2013,70(7):3093-3105

At the Kristineberg mine, northern Sweden, sulphidic mine tailings were remediated in an 8-year pilot-scale experiment using sewage sludge to evaluate its applicability as a sealing layer in a composite dry cover. Sediment, leachate water, and pore gas geochemistry were collected in the aim of determining if the sludge was an effective barrier material to mitigate acid rock drainage (ARD) formation. The sludge was an effective barrier to oxygen influx as it formed both a physical obstruction and functioned as an organic reactive barrier to prevent oxygen to the underlying tailings. Sulphide oxidation and consequential ARD formation did not occur. Sludge-borne trace elements accumulated in a reductive, alkaline environment in the underlying tailings, resulting in an effluent drainage geochemistry of Cd, Cu, Pb and Zn below 10 μg/L, high alkalinity (810 mg/L) and low sulphate (38 mg/L). In contrast, the uncovered reference tailings received a 0.35-m deep oxidation front and typical ARD, with dissolved concentrations of Cd, Zn and sulphate, 20.8 μg/L, 16,100 μg/L and 1,390 mg/L, respectively. Organic matter degradation in the sludge may be a limiting factor to the function of the sealing layer over time as 85 % loss of the organic fraction occurred over the 8-year experimental period due to aerobic and anaerobic degradation. Though the cover may function in the short to medium term (100 years), it is unlikely to meet the demands of a long-term remedial solution.  相似文献   

Multixenobiotic resistance, acetyl-choline esterase activity and total oxyradical scavenging capacity of the Arctic spider crab, Hyasaraneus, following exposure to bisphenol A, tetra bromo diphenyl ether and diallyl phthalate     

Minier C  Forget-Leray J  Bjørnstad A  Camus L 《Marine pollution bulletin》2008,56(8):1410-1415

The Arctic has become a sink for persistent organic pollutants (POPs) originating from lower latitudes, and relatively high levels have been found in different biota. Recent studies have identified detrimental effects on wildlife including endocrine disruption, impairment of enzyme activity, and reduced immune function. The Arctic spider crab, Hyas araneus, shown interesting potential for its use as sentinel organism in polar ecosystems. This study investigated the effect of 2,2',4,4'-tetra bromo diphenyl ether (BPDE), bisphenol A (BPA), and diallyl phthalte (DPA) on H. araneus in a three weeks exposure study. Expression of multixenibiotic resistance (MXR) proteins has been studied using the C219 monoclonal antibody which allows identifying an immunoreactive protein of 40 kDa in the digestive gland while no such protein could be observed in the gills. Expression of this protein was increased by exposure to DPA (+75%; p<0.05, n=10). All compounds significantly affected muscle acetylcholine esterase (AChE) activity (p<0.05, n=10) with 50 microg/L DPA having the strongest effect by lowering the value to 37% of control. The total oxyradical scavenging capacity measured in the digestive gland toward peroxyl, hydroxyl and peroxynitrite was also significantly reduced indicating a decreased resistance to oxidative stress generated by DPA (p<0.05, n=5). These results thus suggest the potential detrimental effects of DPA even at concentration as low as 50 microg/L on H. araneus.  相似文献   

Evaluation of cosmogenic 3He and 21Ne production rates in olivine and pyroxene from two Pleistocene basalt flows,western Grand Canyon,AZ, USA     

Cassandra R. Fenton  Samuel Niedermann  Mirjam M. Goethals  Björn Schneider  Jan Wijbrans 《Quaternary Geochronology》2009,4(6):475-492

Combining cosmogenic ³He and ²¹Ne (³He_c and ²¹Ne_c) measurements on both pyroxene and olivine from the Pleistocene Bar Ten flows (85–107 ka) greatly increases our ability to evaluate the accuracy of ³He_c and ²¹Ne_c production rates and, therefore, ³He_c and ²¹Ne_c surface exposure ages. Comparison of ³He_c and ²¹Ne_c age-pairs yielded by experimentally determined production rates and composition-based model calculations indicates that the former give more accurate surface exposure ages than the latter in this study. However, experimental production rates should be adjusted to the composition of the minerals being analyzed to obtain the best agreement between ³He_c and ²¹Ne_c ages for any given sample. ²¹Ne_c/³He_c values are 0.400 ± 0.029 and 0.204 ± 0.014 for olivine and pyroxene, respectively, in Bar Ten lava flows, in agreement with previously published values, and indicate that ²¹Ne_c/³He_c in olivine and pyroxene is not affected by erosion and remains constant with latitude, elevation, and time (up to 10 Myr). Samples with ²¹Ne_c/³He_c that do not agree with these values may indicate the presence of non-cosmogenic helium and/or neon. The neon three-isotope diagram can also indicate whether or not all excess neon in mineral separates comes from cosmogenic sources. An error-weighted regression for olivine defines a spallation line [y = (1.033 ± 0.031)x + (0.09876 ± 0.00033)], which is indistinguishable from that for pyroxene (Schäfer et al., 1999). We have derived a production rate of 25 ± 8 at/g/yr for ²¹Ne_c in clinopyroxene (En_43–44) based on the ⁴⁰Ar/³⁹Ar age of the upper Bar Ten flow. Our study indicates that the production rate of ²¹Ne_c in olivine may be slightly higher than previously determined. Cosmogenic ³He and ²¹Ne remain extremely useful, particularly when paired, in determining accurate eruption ages of young olivine- and pyroxene-rich basaltic lava flows.  相似文献   

Quartz Cement in Middle Jurassic Reservoir Sandstones in North Sea A Review. Part II： Duration and Silica Sources     

Shao nan Zhang Knut Bj Φ rlykke 《沉积学报》2000,18(1):119-126

The timing and duration of quartz cementation in sandstones have been mainly inferred from diagenetic texture, relationship between pore filling minerals, fluid inclusions and isotopic data. Fluid inclusion temperatures from North Sea reservoir sandstones indicate that most of the quartz cement forms at temperature exceeding 90℃ and is continually proceeding after oil emplacement, based on the fluid inclusion temperatures in quartz overgrowth which is approaching the bottom-hole temperatures. The duration of quartz cement after oil emplacement depends upon the saturation of porewater and the distribution of pore water film and the property of water-wet or oil-wet of the reactants. The leaching of K-feldspar by meteoric water requires pore water flow to move the released potassium and sodium and silica out the solution, which suggests the mechanism does not appear to be a major source of silica for quartz cementation. The quartz cementation coincidence with the compaction and pressure solution suggests the major source of silica. The alteration of feldspar by illitization of kaolinite may serve as another important source of silica at deep burial depth. External sources are not need to call on for illustrating the quartz cementation, because there is no evidences for large scale convection of pore water flow occurred in the burial history of reservoir sandstones of middle Jurassic in the North Sea.  相似文献   

Altimetry-derived tide model for improved tide and water level forecasting along the European continental shelf     

Hart-Davis  Michael G.  Laan  Stendert  Schwatke  Christian  Backeberg  Björn  Dettmering  Denise  Zijl  Firmijn  Verlaan  Martin  Passaro  Marcello  Seitz  Florian 《Ocean Dynamics》2023,73(8):475-491

Ocean Dynamics - With the continued rise in global mean sea level, operational predictions of tidal height and total water levels have become crucial for accurate estimations and understanding of...  相似文献   

Solar Image Restoration By Use Of Multi-frame Blind De-convolution With Multiple Objects And Phase Diversity     

Michiel Van Noort  Luc Rouppe Van Der Voort  Mats G. Löfdahl 《Solar physics》2005,228(1-2):191-215

An extension of Joint Phase Diverse Speckle image restoration is presented. Multiple realizations of multiple objects having known wavefront relations with each other can now be restored jointly. As the alignment of the imaging setup does not change, near-perfect alignment can be achieved between different objects, thus greatly reducing false signals in the determination of derived quantities, such as magnetograms, Dopplergrams, etc. The method was implemented in C++ as an image restoration server, to which worker clients can connect and disconnect randomly, so that a large number of CPUs can be used to speed up the restorations. We present a number of examples of applications of the restoration method to observations obtained with the Swedish 1-m Solar Telescope on La Palma.  相似文献   

Regional climate changes drive increased scaled-chrysophyte abundance in lakes downwind of Athabasca Oil Sands nitrogen emissions     

Graham R. Mushet  Kathleen R. Laird  Biplob Das  Brittany Hesjedal  Peter R. Leavitt  Kenneth A. Scott  Gavin L. Simpson  Björn Wissel  Jared D. Wolfe  Brian F. Cumming 《Journal of Paleolimnology》2017,58(3):419-435

Several limnological and paleolimnological investigations have linked enhanced atmospheric nitrogen (N) deposition to nutrient enrichment and increased primary production. The Athabasca Oil Sands Region (AOSR) in northeast Alberta, Canada is a significant source of N emissions, particularly since development intensified during the 1990s, and recent paleolimnological investigations provide evidence of increased lake production in adjacent areas subject to enhanced N deposition. The AOSR, however, has also experienced atmospheric warming since ca. AD 1900, and therefore the relative effects of nutrient deposition and climate changes on lake production remain unclear. We undertook a factorial-design paleolimnological assessment of 16 lakes in northwest Saskatchewan to quantify changes in abundance and species composition of scaled chrysophytes over the past 100 years. Study sites included both N-limited and P-limited lakes within control regions, as well as lakes that receive enhanced N deposition from the AOSR. We hypothesized that a change in algal communities within N-limited AOSR-impacted lakes, without concurrent changes in the other lake groups, would suggest AOSR-derived N as a driver of enhanced primary production. Instead, marked increases in concentrations of scaled chrysophytes, mainly Mallomonas crassisquama, occurred in the recent sediments in cores from all four lake groups (N-limited vs. P-limited, impacted vs. control), suggesting that regional climate change rather than N deposition was the paramount process enhancing chrysophyte production. Because chrysophyte abundances tended to be higher in deep, lower-pH lakes, and chrysophyte time series were fit best by lake-specific generalized additive models, we infer that climate effects may have been mediated by additional catchment and/or lake-specific processes.  相似文献